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In spherical polar coordinates, the commutation coef cients Cr , Cr , and C are 1 (a) Cr = Cr = r , C = 0 1 (b) Cr = Cr = r , C = tan 1 (c) Cr = Cr = r , C = cot r (d) Cr = Cr = r12 , C = cot r Consider the Tolman metric studied in Example 5-1. The Ricci rotation coef cient r is given by (a) R e (t,r ) R (b) R e (t,r ) R (c) e (t,r ) (t,r ) (d) e R

FIGURE 29.23 Trace surface view and vertical cross section illustrating munchies (or mouse bites ) and pitting.

FIGURE 29.24 PTH vertical cross section illustrating wave-soldering blowholes and thin, rough copper plating.

Solder plate (60 percent tin, 40 percent lead) is widely used as a finish plate on printed circuit boards. This process features excellent etch resistance to alkaline ammonia, good solderability after storage, and good corrosion resistance. Tin-lead plating is used for several types of boards, including tin-lead/copper, tin-lead/tin-nickel/copper, solder mask over bare copper (SMOBC), and surface-mount (SM). Fusing is required on all tin-lead-plated surfaces. Thickness minimums are not specified. The preferred composition contains a minimum of 55 percent and a maximum of 70 percent tin. This alloy is near the tin-lead eutectic, which fuses at a temperature lower than the melting point of either tin or lead and, thus, makes it easy to reflow (fuse) and solder. (The composition of the eutectic is 60 percent tin, 37 percent lead, with a melting point of 361 F.) Fusing processes include infrared (IR), hot oil, vapor phase, and hot-air leveling for SMOBC. Plating solutions currently available include the high-concentration fluoboric acid peptone system as well as low-fluoboric, nonpeptone, and a nonfluoboric organic aryl sulfonic acid process. These processes are formulated to have high throwing power and give uniform alloy composition.1 The sulfonic acid process has the advantage of using ball-shaped tin-lead anodes. Table 29.6 gives details of operation and control of two high-throw tin-lead (solder) baths.

TABLE 29.6 Tin-Lead Fluoborate: Operation and Control High HBF4/peptone Operating conditions Lead Stannous tin (SN+2) Free fluoboric acid Boric acid Additive Temperature Cathode current density Agitation Anodes Type Composition Purity Bags Hooks Length Current density 1.07 1.88 oz./gal 1.61 2.68 oz./gal 47 67 oz./gal Hang bag in tank Use as needed by Hull cell and Ah usage. 60 80 F 15 18 A/ft2 Solution circulation Bar 60% tin-40% lead Federal Specification QQ-S-57130 Polypro Monel Rack length minus 2 in 10 20 A/ft2 Low HBF4/proprietary 1.4 3.0 oz./gal 3.0 4.5 oz./gal 15 25 oz./gal Same Use as needed by Hull cell and Ah usage. 70 85 F 10 30 A/ft2 Mechanical and solution circulation

Filtration A 3 to 10 mm polypro filter is needed to control solution cloudiness and deposit roughness.

Carbon Treatment The solution is batch-treated at room temperature every 4 to 12 months. If the solution is clear and colorless, additive is added based on Hull cell and analysis. Do not use Supercarb or hydrogen peroxide.

Contaminations Several classifications of contaminations are possible:

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Organic Such contamination results from peptone or additive breakdown and plating resists. Periodic carbon treatment is needed. Metallic Copper is the most serious of these contaminations. It causes dark deposits at lowcurrent densities (in the plated through hole) and may coat the anodes. The maximum levels of metallic contaminants allowable are copper, 15 ppm; iron, 400 ppm; and nickel, 100 ppm. Nonmetallic The maximum levels allowed are chloride, 2 ppm; and sulfate, 2 ppm. Dummy Copper is removed by dummy plating at 3 to 5 A/ft2 several hours each week. (Dummy plating is plating at a low-current density, using corrugated metal sheets or scrap panels.) Other metals such as iron and nickel in high concentrations may contribute to dewetting and cannot be easily removed. Ensure that the copper is covered by a tin-lead coating before reducing the current density for dummying.