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Alkaline etchants are followed by treatment with proprietary ammonium chloride acidic solutions, ferric and cupric chloride with solutions of hydrochloric or oxalic acid, and ammonium persulfate with sulfuric acid Alkaline cleaning is used for tin/lead boards etched in chromic sulfuric acid Etchant residue not removed before drying or reflow results in lowered electrical resistance of the dielectric substrate and in poor electrical contact and soldering on the conductive surfaces2 Care must be taken to minimize undercutting and overplating to eliminate slivers of plating breaking off and bridging circuitry A problem common to etching printed boards is not having the entire area etch clean at the same time This occurs when etch action is more rapid at the edges of printed areas than in a broad expanse of copper.

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If very fine patterns and lines are required, the result can be loss of the pattern due to undercutting, especially when the board is left in the etcher until all the field copper has etched away Modern etchers with reduced pooling of etchant have reduced this problem Fine-line boards in high-volume production may require special fine-line etchants, highresolution photoresists, thin-clad laminates, controlled plating distribution, and thin base foil processing Care must be taken to balance etching and thickness factors In some cases, fine-line etchant additives have actually made cleanout more difficult in spaces of 0003 in and narrower..

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The method used for resist stripping must be carefully evaluated when a resist is selected. The effect on board materials, cost and production requirements, and compliance with safety and pollution standards must be taken into account. Solvent-based stripping solutions are under significant environmental pressure. Chlorinated solvents and cyclic compounds (toluene, xylenes, etc.) have been banned, and many glycol ethers are restricted. In spray applications, care must be taken to capture or eliminate VOC emissions. For these reasons, aqueous or primarily aqueous stripping systems are necessarily widely used.

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Now c is a measure of the distance between two inertial particles From elementary physics, you recall that velocity is the time derivative of position, ie, v = dx/dt and acceleration is a = d2 x/dt 2 For inertial geodesics with tangent vector u a and parameter , by analogy, we de ne the relative acceleration between two geodesics by D2 a = u b b (u c c a ) D 2 = u b b ( c c u a ) = u b ( b c c u a + c b c u a ) = u b b c c u a + u b c b c u a We can use (6.

Screen Resist Removal Alkali-soluble resist inks are generally preferred. Stripping in the case of thermal and UVcurable resists is accomplished in 2 percent sodium hydroxide or in proprietary solutions. The resist is loosened and rinsed off with a water spray. Adequate safety precautions must be taken, since caustics are harmful. Conveyorized resist-stripping and etching machines use high-pressure pumping systems that spray hot alkaline solutions on both sides of the boards. Certain laminate materials such as the polyimides may be attached by alkaline strippers. Measling, staining, or other

degradation is noted when strippers attack epoxy or other substrates. Control of concentration, temperature, and dwell time usually can prevent serious problems. Screened vinyl-based resists are removed by a dissolving action in solutions of chlorinated, petroleum, or glycol ether solvents. Methylene chloride and toluene (both currently not usable) were used extensively in cold stripper formulations. The most common strippers are acidic formulations that contain copper brighteners and swelling, dissolution, and water-rinsing agents. The usual procedure for static tank stripping involves soaking the coated boards in at least two tanks of stripper. Excessive time in strippers is to be avoided because of attack on the butter (top epoxy) coat, especially on print-and-etch or single-sided boards. Water is a contaminant in most cold strippers.

Photoresist Removal 34321 Dry Film Dry-film resists have been formulated for ease of removal in aqueousalkaline solutions Strippers are available for both static tank and conveyorized systems, although conveyorized systems are preferred because the spray action aids in separating the resist from the copper surfaces and washing it off the panel Prompt processing after etching avoids resist adhesion lock-in, which can make removal difficult Aqueous-alkaline stripping results in partially undissolved residues of softened resist films These residues are captured in a filter system and disposed off in accordance with waste-disposal requirements Design and availability of specific filters to match the character of the skins can be a significant factor in the selection of the proper resist Environmental caution must be taken to properly evaluate and dispose of resist residues Metal content (particularly lead) may lead to classification of these residues as toxic waste 3432.

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